vuzbiochemiИзвестия вузов. Прикладная химия и биотехнологияProceedings of Universities. Applied Chemistry and Biotechnology2227-29252500-1558ИРНИТУ10.21285/2227-2925-2020-10-2-180-187vuzbiochemi-374Research ArticleХИМИЧЕСКИЕ НАУКИCHEMICAL SCIENCESСинтез и строениe 1-алкокси-1,4-диоксо-2- алкенолятов натрия и бис-(4-алкил(арил)-1-оксо- 1-алкоксиалкан-2,4-дионато)металлов(II) на их основеSynthesis and structure of sodium 1-alkoxy-1,4-dioxo-2-alkenolates and bis-(4-alkyl(aryl)- 1-oxo-1-alkoxyalkane-2,4-dionato) metals (II) based on themКунавинаЕ. А.KunavinaE. A.kea20072007@yandex.ruПешковС. А.PeshkovS. A.
к.х.н., доцент460018, г. Оренбург, пр-т Победы, 13, Российская Федерация
darvin156@mail.ruИскандаровА. Ю.IskandarovA. Yu.oybekiskandarov@mail.ruОренбургский государственный университетРоссияOrenburg State UniversityRussian FederationТашкентский государственный педагогический университетУзбекистанTashkent State Pedagogical UniversityUzbekistan202002072020102180187Copyright © Кунавина Е.А., Пешков С.А., Искандаров А.Ю., 20202020Кунавина Е.А., Пешков С.А., Искандаров А.Ю.Kunavina E.A., Peshkov S.A., Iskandarov A.Y.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vuzbiochemi.elpub.ru/jour/article/view/374оксоеноляты натрияметаллокомплексысинтезспектральный анализsodium oxoenolatesmetal complexessynthesisspectral analysisReferencesPopov L.D., Morozov A.N., Shcherbakov I.N., Tupolova Yu.P., Lukov V.V., Kogan V.A. Metal complexes with polyfunctional ligands based of bis(hydrazones) of dicarbonyl compounds // Russian Chemical Reviews. 2009. Vol. 78. Issue 7. P. 643–658. https://doi.org/10.1070/RC2009v078n07ABEH003890Popov LD, Morozov AN, Shcherbakov IN, Tupolova YuP, Lukov VV, Kogan VA. Metal complexes with polyfunctional ligands based of bis(hydrazones) of dicarbonyl compounds. Russian Chemical Reviews. 2009;78(7):643–658. https://doi.org/10.1070/RC2009v078n07ABEH003890Levchenkov S.I., Shcherbakov I.N., Popov L.D., Lyubchenko S.N., Tsaturyan A.A., Beloborodov S.S., et al. Transition metal comple-xes with 2,6-di-tert-butyl-p-quinone 1′-phthalazinylhydrazone // Russian Journal of General Chemistry. 2013. Vol. 83. Issue 10. P. 1928–1936. https://doi.org/10.1134/S1070363213100216Levchenkov SI, Shcherbakov IN, Popov LD, Lyubchenko SN, Tsaturyan AA, Beloborodov SS, et al. Transition metal complexes with 2,6-di-tert-butyl-p-quinone 1′-phthalazinylhydrazone. Russian Journal of General Chemistry. 2013;83(10):1928–1936. https://doi.org/10.1134/S1070363213100216Burlov A.S., Zaichenko S.B., Popov L.D., Vlasenko V.G., Borodkin G.S., Makarova N.I., et al. Synthesis, structure, and spectral properties of 3,5-di-tert-butyl-1,2-benzoquinone 3-hydroxynaphthoylhydrazone and Its complexes with Zn(II), Cd(II), Ni(II), Co(II) // Russian Journal of General Chemistry. 2019. Vol. 89. Issue 4. P. 727–735. https://doi.org/10.1134/S1070363219040157Burlov AS, Zaichenko SB, Popov LD, Vlasenko VG, Borodkin GS, Makarova NI, et al. Synthesis, Structure, and spectral properties of 3,5-di-tert-butyl-1,2-benzoquinone 3-hydroxynaphthoylhydrazone and Its complexes with Zn(II), Cd(II), Ni(II), Co(II). Russian Journal of General Chemistry. 2019;89(4):727–735. https://doi.org/10.1134/S1070363219040157Popov L.D., Shcherbakov I.N., Tupolova Y.P., Etmetchenko L.N., Kogan V.A., Levchenkov S.I., et al. Copper(II) complexes with N-(phenyl)alkylthiosemicarbazones of 3,5-dichlo-ro- and 3,5-diiodosalicylic aldehydes // Russian Journal of General Chemistry. 2016. Vol. 86. Issue 2. P. 344–348. https://doi.org/10.1134/ S1070363216020249Popov LD, Shcherbakov IN, Tupolova YP, Etmetchenko LN, Kogan VA, Levchenkov SI, et al. Copper(II) complexes with N-(phenyl)alkylthiosemicarbazones of 3,5-dichloro- and 3,5-diiodosalicylic aldehydes. Russian Journal of General Chemistry. 2016;86(2):344–348. https://doi.org/10.1134/S1070363216020249Shcherbakov K.V., Burgart Ya.V., Saloutin V.I. Metal complexes based on functionalized 4-hydroxypolyfluorocoumarins // Russian Journal of Organic Chemistry. 2014. Vol. 50. Issue 6. P. 815–821. https://doi.org/10.1134/S1070428014060104Shcherbakov KV, Burgart YaV, Saloutin VI. Metal complexes based on functionalized 4-hydroxypolyfluorocoumarins. Russian Journal of Organic Chemistry. 2014;50(6):815–821. https://doi.org/10.1134/S1070428014060104Melkozerov S.A., Pervova I.G., Lipunov I.N., Dvoskin E.A., Lipunova G.N., Barachevskii V.A. Synthesis and photoluminescence properties of zinc(II) complexes with salicylaldehyde hetarylhydrazones // Russian Journal of General Chemistry. 2013. Vol. 83. Issue 4. P. 646–651. https://doi.org/10.1134/S1070363213040063Melkozerov SA, Pervova IG, Lipunov IN, Dvoskin EA, Lipunova GN, Barachevskii VA. Synthesis and photoluminescence properties of zinc(II) complexes with salicylaldehyde hetarylhydrazones. Russian Journal of General Chemistry. 2013;83(4):646–651. https://doi.org/10.1134/S1070363213040063Kudyakova Yu.S., Goryaeva M.V., Burgart Ya.V., Saloutin V.I. Asymmetric azomethine ligands based on 2-[(2-aminophenyl)aminomethylidene]-3-oxo-3- polyfluoroalkylpropionates and aldehydes // Russian Chemical Bulletin. 2010. Vol. 59. Issue 9. P. 1753–1760. https://doi.org/10.1007/s11172-010-0308-8Kudyakova YuS, Goryaeva MV, Burgart YaV, Saloutin VI. Asymmetric azomethine ligands based on 2-[(2-aminophenyl)aminomethylidene]-3-oxo-3-polyfluoroalkylpropionates and aldehydes. Russian Chemical Bulletin. 2010;59(9):1753–1760. https://doi.org/10.1007/s11172-010-0308-8Metelitsa A.V., Burlov A.S., Borodkina I.G., Bren V.A., Garnovskii A.D., Minkin V.I., et al. Luminescent complexes with ligands containing C=N bond // Russian Journal of Coordination Chemistry. 2006. Vol. 32. Issue 12. P. 858–868. https://doi.org/10.1134/S1070328406120025Metelitsa AV, Burlov AS, Borodkina IG, Bren VA, Garnovskii AD, Minkin VI, et al. Luminescent complexes with ligands containing C=N bond. Russian Journal of Coordination Chemistry. 2006;32(12):858–868. https://doi.org/10.1134/S1070328406120025Blokhin Y.I., Lyubimov I.A., Bagautdinov A.M., Abramov I.A., Khotina I.A., Karnoukhova V.A. Copper(I) complexes with phenylphosphonous acid diamide // Russian Journal of Coordination Chemistry. 2016. Vol. 42. Issue 6. P. 372–377. https://doi.org/10.1134/S1070328416060014Blokhin YI, Lyubimov IA, Bagautdinov AM, Abramov IA, Khotina IA, Karnoukhova VA. Copper(I) complexes with phenylphosphonous acid diamide. Russian Journal of Coordination Chemistry. 2016;42(6):372–377. https://doi.org/10.1134/S1070328416060014Yang T., Niu F., Li L.X., Xia Z.N., Zhang Y., You Z.L. Synthesis, characterization, crystal structures, and antimicrobial activity of cobalt(II) and iron(III) complexes derived from n-(2-hydroxybenzylidene)-3-methylbenzohydrazide // Russian Journal of Coordination Chemistry. 2016. Vol. 42. Issue 6. P. 402–409. https://doi.org/10.1134/S1070328416050109Yang T, Niu F, Li LX, Xia ZN, Zhang Y, You ZL. Synthesis, characterization, crystal structures, and antimicrobial activity of cobalt(II) and iron(III) complexes derived from n-(2-hydroxybenzylidene)-3-methylbenzohydrazide. Russian Journal of Coordination Chemistry. 2016;42(6): 402–409. https://doi.org/10.1134/S1070328416050109Кувшинова Е.М., Быкова М.А., Вершинина И.А., Горнухина О.В., Любимова Т.В., Семейкин А.С. Синтез и координационные свойства кобальтовых комплексов 5-фенил-2,3,7,8,12,18-гексаметил-13,17-диэтилпорфина и его нитрозамещенных в органических растворителях // Известия высших учебных заведений. Серия: Химия и химическая технология. 2018. Т. 61. N 7. С. 44–49. https://doi.org/10.6060/ ivkkt.20186107.5843Kuvshinova EM, Bykova MA, Vershinina IA, Gornukhina OV, Lyubimova TV, Semeykin AS. Synthesis and coordination properties of cobalt complexes of 5-phenyl-2,3,7,8,12,18-hexamethyl-13,17-diethylporphine and its nitrosubstituted in organic solvents. Izvestiya Vysshikh Uchebnykh Zavedenii. Khimiya i Khimicheskaya Tekhnologiya = Russian Journal of Chemistry and Chemical Technology. 2018;61(7):44–49. (in Russian) https://doi.org/ 10.6060/ivkkt.20186107.5843Кudayarova Т.V., Тyutina M.A., Danilova Е.А. Сomplexes of izothiadiazole- containing bromonitrosubstituted three units product with d-metals (Ni, Co, Zn) // Известия высших учебных заведений. Серия: Химия и химическая технология. 2018. Т. 61. N 12. С. 68–73. https://doi.org/10.6060/ivkkt.20186112. 5799Кudayarova Т.V., Тyutina M.A., Danilova Е.А. Complexes of izothiadiazole-containing bromonitrosubstituted three units product with d-metals (Ni, Co, Zn). Izvestiya Vysshikh Uchebnykh Zavedenii. Khimiya i Khimicheskaya Tekhnologiya = Russian Journal of Chemistry and Chemical Technology. 2018;61(12):68–73. https://doi.org/10.6060/ivkkt.20186112.5799Chizhova N.V., Ivanova Yu.B., Mamardashvili N.Z., Rusanov A.I., Khrushkova Y.V. Synthesis and spectral and fluorescent properties of metal complexes of octakis(4-Chizhova NV, Ivanova YuB, Mamardashvili NZ, Rusanov AI, Khrushkova YV. Synthesis and spectral and fluorescent properties of metal complexes of octakis(4-flurophenyl)tetraazaporphyrins. Russian Journal of Organic Chemistry. 2019; 55(5):655–661. https://doi.org/10.1134/S1070428019050129flurophenyl)tetraazaporphyrins // Russian Journal of Organic Chemistry. 2019. Vol. 55. Issue 5. P. 655–661. https://doi.org/10.1134/S1070428019050129Seifullina II, Martsinko EÉ, Chebanenko EA, Gridina TL, Mudrik LM, Fedchuk AS. Antiviral properties of the new coordination compound silver bis(citrato)germanate. Pharmaceutical Chemistry Journal. 2019;53(4):318–321. https://doi.org/10.1007/s11094-019-01999-wSeifullina I.I., Martsinko E.É., Chebanenko E.A., Gridina T.L., Mudrik L.M., Fedchuk A.S. Antiviral properties of the new coordination compound silver bis(citrato)germanate // Pharmaceutical Chemistry Journal. 2019. Vol. 53. Issue 4. P. 318–321. https://doi.org/10.1007/s11094-019-01999-wMustafina AR, Skripacheva VV, Konovalov AI. Outer-sphere association of calixarenes and other macrocyclic ligands with metal complexes as the basis for the design of molecular devices. Russian Chemical Reviews. 2007; 76(10): 917–930. http://dx.doi.org/10.1070/RC2007v076n10ABEH003727Mustafina A.R., Skripacheva V.V., Konovalov A.I. Outer-sphere association of calixarenes and other macrocyclic ligands with metal complexes as the basis for the design of molecular devices // Russian Chemical Reviews. 2007. Vol. 76. Issue 10. P. 917–930. http://doi.org/10.1070/RC2007v076n10ABEH003727Amerkhanova ShК, Nurkenov ОА, Uali АS, Satpaeva ZhB, Abdiken FS. And complex formation ability of n-2-(2-ydroxyben-zoyl)hydrazinocarbonotioilbenzamide towards to La3+, Y3+, Nd3+ ions in binary mixture “water–1,4-dioxane”. Izvestiya Vuzov. Prikladnaya Khimiya i Biotekhnologiya = Proceedings of Universities. Applied Chemistry and Biotechnology. 2016;6(4):9–14. (In Russian) https://doi.org/10.21285/2227-2925- 2016-6-4-9-14Амерханова Ш.К., Нуркенов О.А., Уали А.С., Сатпаева Ж.Б., Абдикен Ф.С.Peshkov SA, Khursan SL. Complexation of the Zn, Co, Cd, and Pb ions by metallothioneins: A QM/MM simulation. Computational and Theoretical Chemistry. 2017;1106:1–6. http://doi.org/10.1016/j.comptc.2017.02.029Синтез и комплексообразующая способность n-2-(2-гидроксибензоил)-гидразинокарбонотиоилбензамида (II) по отношению к ионам La3+, Y3+, Nd3+ в бинарной смеси «вода–1,4-диоксан» // Известия вузов. Прикладная химия и биотехнология. 2016. Т. 6. N 4. С. 9–14. https://doi.org/10.21285/2227-2925-2016-6-4-9-14Синтез и комплексообразующая способность n-2-(2-гидроксибензоил)-гидразинокарбонотиоилбензамида (II) по отношению к ионам La3+, Y3+, Nd3+ в бинарной смеси «вода–1,4-диоксан» // Известия вузов. Прикладная химия и биотехнология. 2016. Т. 6. N 4. С. 9–14. https://doi.org/10.21285/2227-2925-2016-6-4-9-14Peshkov S.A., Khursan S.L. Complexation of the Zn, Co, Cd, and Pb ions by metallothioneins: A QM/MM simulation // Computational and Theoretical Chemistry. 2017. Vol. 1106. P. 1–6. http://doi.org/10.1016/ j.comptc.2017.02.029Peshkov S.A., Khursan S.L. Complexation of the Zn, Co, Cd, and Pb ions by metallothioneins: A QM/MM simulation // Computational and Theoretical Chemistry. 2017. Vol. 1106. P. 1–6. http://doi.org/10.1016/ j.comptc.2017.02.029
The authors declare that there are no conflicts of interest present.