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Production of fuel-grade hydrocarbons from renewable raw materials

https://doi.org/10.21285/achb.906

EDN: WVBXFJ

Abstract

One of the actively developing areas in the current production of motor fuel components from renewable raw materials consists in the processing of vegetable oils using various catalytic processes. The object of research in this paper was rapeseed oil and the products of its processing on a hydrotreating catalyst. The choice of rapeseed oil as a raw material for processing is due to the large acreage it occupies on the territory of the Russian Federation as food industry, currently being produced mainly for export. The authors investigated a process of catalytic processing of rapeseed oil using a hydrotreating catalyst. The processing was carried out in a laboratory catalytic unit at a temperature of 375 °C, a pressure of 7 MPa, and a volume feed rate of 1 h-[1]; the hydrogen consumption was 2×10-4 m3/h Physicochemical and low-temperature properties were determined for the feedstock and catalytic processing product. In addition, the component composition was determined for the resulting catalytic reprocessing product. The main directions of chemical transformations of rapeseed oil components into hydrocarbons on a hydrotreating catalyst are considered. The possibility of using rapeseed oil as a feedstock for producing fuel hydrocarbons – in particular n-alkanes, iso-alkanes and alkenes, which are promising raw materials for the production of motor fuel components – is substantiated. 

 
 
 

About the Authors

D. V. Sosnina
National Research Tomsk Polytechnic University
Russian Federation

Daria V. Sosnina, Postgraduate Student, Engineer

30, Lenin Ave., Tomsk, 634050

   


A. A. Altynov
National Research Tomsk Polytechnic University
Russian Federation

Andrey A. Altynov, Engineer

30, Lenin Ave., Tomsk, 634050

   


Yu. S. Kokorina
National Research Tomsk Polytechnic University
Russian Federation

Yulia S. Kokorina, Student

30, Lenin Ave., Tomsk, 634050

   


M. V. Kirgina
National Research Tomsk Polytechnic University
Russian Federation

Maria V. Kirgina, Cand. Sci. (Engineering), Associate Professor

30, Lenin Ave., Tomsk, 634050

   


I. A. Bogdanov
National Research Tomsk Polytechnic University
Russian Federation

Ilya A. Bogdanov, Assistant

30, Lenin Ave., Tomsk, 634050

   


References

1. Vertakova Yu.V. Alternative energy. Development of a green economy in the energy sector. In: Energeticheskaya bezopasnost’: sb. nauch. statei II Mezhdunar. molodezh. kongr. = Energy security: Proc. of the 2nd International Youth Congress. 28–29 November 2017, Kursk. Kursk: Universitetskaya kniga; 2017, p. 24-26. (In Russian). EDN: YUZCFN.

2. Sharova S.S. The “green” economy is the process of transition of world economies to the development of socio-economic green resources the “green” economy is the process of transition of world economies to the development of socio-economic green resources. Mirovaya ekonomika: problemy bezopasnosti = World Economy: Security Problems. 2021;2:81-84. (In Russian). EDN: MXXNLM.

3. Berenblyum A.S., Podoplelova T.A., Shamsiev R.S., Katsman E.A., Danyushevsky V.Ya., Flid V.R. Catalytic chemistry of preparation of hydrocarbon fuels from vegetable oils and fats. Kataliz v promyshlennosti = Catalysis in Industry. 2012;3:84-91. (In Russian). EDN: NOLWUH.

4. Andreev O.S. Erneuerbare energiequellen und probleme der entwicklung von nicht-konventionellen energiequellen. Konkurentospoosbnost’ v global’nom mire: ekonomika, nauka, tekhnologii = Competitiveness in the global world: economics, science, technology. 2023;2:200-203. (In Russian). EDN: GUWSHK.

5. Bekulova S.R. Renewable energy sources in the new industrial revolution: world and domestic experience. Mir novoi ekonomiki = The world of new economy. 2019;13(4):14-21. (In Russian). DOI: 10.26794/22206469-2019-13-4-14-21. EDN: OOMEKA.

6. Rokov A., Lokhimovich E. Economic aspects of developing renewable energy sources. Strategii biznesa = Business Strategies. 2020;8(2):55-59. (In Russian). DOI: 10.17747/2311-7184-2020-2-55-59. EDN: FLOHOB.

7. Lipin P.V., Potapenko O.V., Sorokina T.P., Doronin V.P. Key features of cotransformation of vacuum gas oils and vegetable oils on dual-zeolite cracking catalysts. Neftekhimiya. 2019. T. 59. N 4. S. 367–377. (In Russian). DOI: 10.1134/S0028242119040099. EDN: GWTKMU.

8. Sosnina D.V., Belozertzeva N.E., Altynov A.A., Bogdanov I.A., Kirgina M.V. Investigation of co-processing of the straight-run diesel fraction and sunflower oil over a zeolite catalyst of ZSM-5 type. Chemistry for Sustainable Development. 2022;30(4):408-414. DOI: 10.15372/CSD2022398. EDN: JKGKHV.

9. Mamedova T.A., Andrushenko N.K., Lyatifova T.S., Askerova E.N., Teyubov Kh.Sh., Kesemenli Kh.G. Production of catalytic cracking gasoline by processing the mixture of petroleum and vegetable raw material. Neftepererabotka i neftekhimiya. Nauchno-tekhnicheskie dostizheniya i peredovoi opyt. 2012;11:15-18. (In Russian). EDN: PWLDXF.

10. Dada T.K., Vuppaladadiyam A., Duan A.X., Kumar R., Antunes E. Probing the effect of Cu-SrO loading on catalyst supports (ZSM-5, Y-zeolite, activated carbon, Al2O3, and ZrO2) for aromatics production during catalytic co-pyrolysis of biomass and waste cooking oil. Bioresource Technology. 2022;360:127515. DOI: 10.1016/j.biortech.2022.127515.

11. Li C., Ma J., Xiao Z., Stanton H., Liu R., Zuo S., et al. Catalytic cracking of Swida wilsoniana oil for hydrocarbon biofuel over Cu-modified ZSM-5 zeolite. Fuel. 2018;218:59-66. DOI: 10.1016/j.fuel.2018.01.026.

12. Zhao X., Wei L., Julson J., Qiao Q., Dubey A., Anderson G. Catalytic cracking of non-edible sunflower oil over ZSM-5 for hydrocarbon bio-jet fuel. New Biotechnology. 2015;32(2):300-312. DOI: 10.1016/j.nbt.2015.01.004.

13. Smirnov A., Wang W., Kikhtyanin O., Xiao L., Wu W., Kubička D. Hydroconversion of sunflower oil to fatty alcohols and hydrocarbons using CuZn and CuZnHBEA-based catalysts. Catalysis Today. 2023;424:113841. DOI: 10.1016/j.cattod.2022.07.009.

14. Ostrikov A.N., Gorbatova A.V., Kopylov M.V., Anikin A.A. Quality parameters of rapeseed cold pressed oil. Pishchevaya promyshlennost’ = Food Industry. 2017;9:52-55. (In Russian). EDN: ZGWTAR.

15. Ostrikov A.N., Gorbatova A.V., Anikin A.A., Kopylov M.V. Analysis of fatty acid composition of rapeseed oil. Maslozhirovaya promyshlennost’. 2016;6:18-21. (In Russian). EDN: XFWDBP.

16. Katikaneni S.P.R., Adjaye J.D., Idem R.O., Bakhshi N.N. Catalytic conversion of canola oil over potassium-impregnated HZSM-5 catalysts: C2-C4 olefin production and model reaction studies. Industrial & Engineering Chemistry Research. 1996;35(10):33323346. DOI: 10.1021/ie950740u.

17. Li Z., Wang W., Liu X., Qi S., Lan D., Wang Y. Effect of different degumming on the retention of bioactive components, acylglycerol and phospholipid composition of rapeseed oil. Process Biochemistry. 2023;133:190199. DOI: 10.1016/j.procbio.2023.08.019.

18. Belozertseva N.E., Torchakova O.M., Bogdanov I.A., Kirgina M.V. Feasibility study of using biodiesel fuels as a blendstock of commercial diesel fuels. Izvestiya Vuzov. Prikladnaya Khimiya i Biotekhnologiya = Proceedings of Universities. Applied Chemistry and Biotechnology. 2022;12(1):130-140. (In Russian). DOI: 10.21285/22272925-2022-12-1-130-140. EDN: WJTELR.

19. Sosnina D.V., Bogdanov I.A., Altynov A.A. Fuel components production by processing of diesel fraction and rapeseed oil blends on zeolite catalyst. In: Khimiya i khimi-cheskaya tekhnologiya v XXI veke: materialy XXIV Mezhdunar. nauch.-prakt. Konf. studentov i molodykh uchenykh im. vydayushchikhsya khimikov L.P. Kuleva i N.M. Kizhnera, posvyashch. 85-letiyu so dnya rozhdeniya prof. A.V. Kravtsova = Chemistry and chemical technology in the 21st century: Proc. of the 24th International Scientific and Practical Conference of Students and Young Scientists named after outstanding chemists L.P. Kulev and N.M. Kizhner, dedicated to 85 anniversary of prof. A.V. Kraftsov. 15–19 May 2023, Tomsk. Tomsk: National Research Tomsk Polytechnic University; 2023, vol. 2, p. 118-119. (In Russian). EDN: MSZBSS.

20. Sosnina D.V., Altynov A.A., Kirgina M.V., Bogdanov I.A. Production components of fuels by catalytic processing of diesel fraction and rapeseed oil blends. Polzunovskii vestnik. 2023;4:237-243. (In Russian). DOI: 10.25712/ASTU.2072-8921.2023.04.030. EDN: NJFSDQ.


Review

For citations:


Sosnina D.V., Altynov A.A., Kokorina Yu.S., Kirgina M.V., Bogdanov I.A. Production of fuel-grade hydrocarbons from renewable raw materials. Proceedings of Universities. Applied Chemistry and Biotechnology. 2024;14(1):121-128. (In Russ.) https://doi.org/10.21285/achb.906. EDN: WVBXFJ

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ISSN 2227-2925 (Print)
ISSN 2500-1558 (Online)