Study of buckwheat husk application for water demineralisation
https://doi.org/10.21285/2227-2925-2020-10-2-213-222
Abstract
In the present paper, a brief review of the scientific literature on the main research directions in the field of sorption filters used for water demineralisation is presented. Materials used for these purposes, both of mineral and organic origin, are considered. Various natural materials, including waste products from wood processing and agriculture, are promising raw materials for the production of sorbents. Since these materials are typically characterised by low sorption ability in their raw form, additional activation processes are required. In this connection, research was conducted by the authors on the sorption of hardness salts (calcium and magnesium) from aqueous solutions in static conditions using raw and chemically modified buckwheat husk in a concentration range from 2 to 40 mEq/dm3. Hydrochloric and phosphoric acids, as well as sodium hydroxide, were used as modifiers. A study of the sorption kinetics demonstrated that the system achieves equilibrium within 5 min from the start of sorption. Additionally, the possibility of maximum demineralisation of aqueous solutions was studied. The best sorption properties with respect to hardness salts were demonstrated by buckwheat husks modified by sodium hydroxide, which had a maximum sorption capacity of 2.4 mEq/dm3 as compared to 2.0 mEq/dm3 for raw husks. For all types of obtained materials, mineral sorption isotherms were constructed in the range of studied concentrations. These isotherms were established to be of S4 type according to the Giles classification. Mathematical processing was carried out according to the sorption models of Langmuir, Freundlich, BET and Dubinin-Radushkevich. The sorption process for calcium and magnesium cations was revealed to be most accurately described by the Freundlich equation.
About the Authors
V. A. Somin
Polzunov Altai State Technical University
Russian Federation
Russian Federation
Dr. Sci. (Engineering), Associate Professor, Head of the Department of Chemical Technique and Environmental Engineering
46, Lenin Ave., Barnaul, 656038, Russian Federation
L. F. Komarova
Polzunov Altai State Technical University
Russian Federation
Dr. Sci. (Engineering), Professor Department of Chemical Technique and Environmental Engineering
46, Lenin Ave., Barnaul, 656038, Russian Federation
Russian Federation
Dr. Sci. (Engineering), Professor Department of Chemical Technique and Environmental Engineering
46, Lenin Ave., Barnaul, 656038, Russian Federation
A. V. Kutalova
Polzunov Altai State Technical University
Russian Federation
Master Student
46, Lenin Ave., Barnaul, 656038, Russian Federation
Russian Federation
Master Student
46, Lenin Ave., Barnaul, 656038, Russian Federation
References
1. Vigdorovich VI, Tsygankova LE, Morshinina IV. Regularities of Ca (II) and Mg (II) cations sorption by GBMTO glauconite concentrate. Sorbtsionnye i Khromatograficheskie Protsessy = Sorption and Chromatography Processes. 2014;14(2):286–295. (In Russian)
2. Vigdorovich VI, Esina MN, Shel NV, Tsygankova LE, Popova AN. Sorption of calcium and magnesium cations on glauconite from running chloride solutions. Sorbtsionnye i Khromatograficheskie Protsessy = Sorption and Chromatography Processes. 2016;16(4):533–543. (In Russian)
3. Somin VA, Kurtukova LV, Komarova LF. Groundwater softening using a new sorbent based on bentonite clays. Ekologiya i promyshlennost' Rossii = Ecology and Industry of Russia. 2015;19(1):30–33. (In Russian)
4. Mostalygina LV, Elizarova SN, Tikhonova AYu, Kostin AV. Regulation of calcium and magnesium ions concentration by natural sorbent – bentonitic clay. Izvestiya Samarskogo nauchnogo centra RAN = Izvestia of Samara Scientific Center of the Russian Academy of Sciences. 2010;2(1):1042–1045. (In Russian)
5. Somin VA, Betz SA, Komarova LF. The Use of Sorbents Based on Natural Raw Materials for the Purification of Phenol-Containing Waters. Ekologia i promyshlennost Rossii = Ecology and Industry of Russia. 2016;20(12):14–17. (In Russian) https://doi.org/10.18412/1816-0395-2016-12-14-17
6. Shilina AS, Bakhtin VD, Burukhin SB, Askhadullin SR. Sorption of cations the heavy metals and radionuclides from the aqueous medium with new synthetic zeolite-similar sorbent. Izvestiya vuzov. Yadernaya energetika. 2017;1:116–126. (In Russian) https://doi.org/10.26583/npe.2017.1.11
7. Wang B, Li F, Yang P, Yang Y, Hu J, Wei J, et al. In Situ Synthesis of Diatomite-Carbon Nanotube Composite Adsorbent and Its Adsorption Characteristics for Phenolic Compounds. Journal of Chemical and Engineering Data. 2019;64(1):360–371. https://doi.org/10.1021/acs.lced.8b00874
8. Ahsan A, Jabbari V, Islam MT, Turley RS, Dominguez N, Kim H, et al. Sustainable synthesis and remarkable adsorption capacity of MOF/graphene oxide and MOF/CNT based hybrid nanocomposites for the removal of Bisphenol A from water. Science of the Total Environment. 2019;673:306–317. https://doi.org/10.1016/j.scitotenv.2019.03.219
9. Smyatskaya YA, Politaeva NA, Shaikhiev IG, Sverguzova SV. Sorption composites cleaning waste water of heavy-metal ions. Vestnik tekhnologicheskogo universiteta. 2018;21(2):215–219. (In Russian)
10. Smyatskaya YuA, Fazullina AA, Politaeva NA, Zhazhkov VV, Pavlushkina YuE, Dolbnya IV. The Use and Utilization of Chitosan Sorbents – the Residual Biomass of Microalgae Chlorella Sorokiniana. Ekologia i promyshlennost Rossii = Ecology and Industry of Russia. 2019;23(9):18–23. (In Russian) https://doi.org/10.18412/1816-0395-2019-9-18-23
11. Shaimardanova ASh, Stepanova SV, Shaikhiev IG. Study of reusability of leaf litter as a sorption material in relation to iron ions. Izvestiya Vuzov. Prikladnaya Khimiya I Biotekhnologia = Proceeding of Universities. Applied Chemistry and Biotechnology. 2017;7(2):164–172. (In Russian) https://doi.org/10.21285/2227-2925-2017-7-2-164-172
12. Yuvaraja G., Munagapati V.S., Naushad M., Abburi K. Removal of Ni(II) from aqueous solution by Lycopersicum esculentum (Tomato) leaf powder as a low-cost biosorbent. Desalination and Water Treatment. 2015;54(1):200–208. https://doi.org/10.1080/19443994.2014.880160
13. Yuvaraja G., Krishnaiah N., Subbaiah M.V., Krishnaiah A. Biosorption of Pb(II) from aqueous solution by Solanum melongena leaf powder as a low-cost biosorbent prepared from agricultural waste. Colloids and Surfaces B: Biointerfaces. 2014;114:75–81. https://doi.org/10.1016/j.colsurfb.2013.09.039
14. Chernysheva EA, Grabelnykh VA, Levanova EP, Korchevin NA. The using of sulfurcontaining lignin based sorbent for extraction of mercury from aqueous solutions. Izvestiya Vuzov. Prikladnaya Khimiya i Biotekhnologia = Proceeding of Universities. Applied Chemistry and Biotechnology. 2017;7(3):169–177. (In Russian) https://doi.org/10.21285/2227-2925-2017-7-3-169-177
15. Aslamova VS, Chernysheva EA, Grabelnykh VA, Levanova EP, Russavskaya NV. Regression analysis of zinc and cadmium ion extraction from aqueous solutions using a lignin-based sulphur-containing sorbent. Izvestiya Vuzov. Prikladnaya Khimiya I Biotekhnologia = Proceeding of Universities. Applied Chemistry and Biotechnology. 2018;8(4):174–183. https://doi.org/10.21285/2227-2925-2018-8-4-174-183
16. Kamalova NA, Galimova RZ, Shaykhiev IG, Sadykova SV, Grechina AS. Sorption of copper and nickel ions by Larix Sibirica needles. Vestnik tekhnologicheskogo universiteta. 2017;20(19): 121–124. (In Russian)
17. Jeon C, Solis KL, An H-R, Hong Y, Igalavithana AD, Ok YS. Sustainable removal of Hg(II) by sulfur-modified pine-needle biochar. Journal of Hazardous Materials. 2020;388:122048. https://doi.org/10.1016/j.jhazmat.2020.122048
18. Xu Y, Su Q, Shen H, Xu G. Physicochemical and sorption characteristics of poplar seed fiber as a natural oil sorbent. Textile Research Journal. 2019;89(19-20):4186–4194. https://doi.org/10.1177/0040517519829001
19. Adekola FA, Hodonou DSS, Adegoke HI. Thermodynamic and kinetic studies of biosorption of iron and manganese from aqueous medium using rice husk ash. Applied Water Science. 2016;6(4):319–330. https://doi.org/10.1007/s13201-014-0227-1
20. Pena J, Villot A, Gerente C. Pyrolysis chars and physically activated carbons prepared from buckwheat husks for catalytic purification of syngas. Biomass and Bioenergy. 2020;132:105435. https://doi.org/10.1016/j.biombioe.2019.105435
21. Politaeva N, Smyatskaya Y, Safonova E, Barsukova N. Influence of wheat husk modification on sorption properties of heavy metal ions. In: 10th International Scientific and Practical Conference: Water Power Energy Forum 2018, 29 October – 2 November 2018, Kazan: IOP Conference Series: Earth and Environmental Science; 2019. https://doi.org/10.1088/1755-1315/288/1/012023
22. Cheng L, Sun L, Xue W, Zeng Z, Li S. Adsorption equilibrium and kinetics of Pb(II) from aqueous solution by modified walnut shell. Environmental Progress and Sustainable Energy. 2016;35(6):1724–1731. https://doi.org/10.1002/ep.12424
23. Sahibzada KI, Saeed A, Kalim I, Iqbal M. Ion-exchange mechanism in biosorption of Pb2+ ions from contaminated water by banana stalk waste. Environmental Engineering and Management Journal. 2016;15(12):2741–2751.
24. Kibami D. Kinetics and adsorption studies of lead (Ii) onto activated carbon using low cost adsorbents. Global NEST Journal. 2018;20(2):381–388. https://doi.org/10.30955/gnj.002532
25. Yang F, Li W, Liu C, Wang M, Li Q, Sun Y. Impact of total carbon/sulfate on methane production and sulfate removal from co-digestion of sulfate-containing wastewater and corn stalk. Journal of Environmental Management. 2019;243: 411–418. https://doi.org/10.1016/j.jenvman.2019.04.129
26. Erdem M, Duran H, Şahin M, Ozdemir I. Kinetics, thermodynamics, and isotherms studies of Cd(II) adsorption onto grape stalk. Desalination and Water Treatment. 2015;54(12):3348–3357. https://doi.org/10.1080/19443994.2014.907753
27. Ali A, Saeed K, Mabood F. Removal of chromium (VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent. Alexandria Engineering Journal (AEJ). 2016;55():2933–2942. https://doi.org/10.1016/j.aej.2016.05.011
28. Abedi M, Salmani MH, Mozaffari SA. Adsorption of Cd ions from aqueous solutions by iron modified pomegranate peel carbons: kinetic and thermodynamic studies. International Journal of Environmental Science and Technology. 2016;13(8):2045–2056. https://doi.org/10.1007/s13762-016-1002-7
29. Yarusova SB, Gordienko PS, Panasenko AE, Barinov NN, Zemnukhova LA. Sorption Properties of Sodium and Potassium Aluminosilicates from Alkaline Hydrolyzates of Rice Straw. Russian Journal of Physical Chemistry. 2019;93(2):333–337. https://doi.org/10.1134/S003602441902033X
30. Chen J, Yang P, Song D, Yang S, Zhou L., Han L, Lai B. Biosorption of Cr(VI) by carbonized Eupatorium adenophorum and Buckwheat straw: thermodynamics and mechanism. Frontiers of Environmental Science and Engineering. 2014;8(6):960–966. https://doi.org/10.1007/s11783-013-0612-2
31. Song D, Pan K, Tariq A, Li Z, Xiong Q. Adsorptive removal of toxic chromium from wastewater using wheat straw and Eupatorium adenophorum. PLoS ONE. 2016;11(12):e0167037. https://doi.org/10.1371/journal.pone.0167037
32. Li Y, Tsend N, Li T, Liu H, Yang R, Gai X, et al. Microwave assisted hydrothermal preparation of rice straw hydrochars for adsorption of organics and heavy metals. Bioresource Technology. 2019;273:136–143. https://doi.org/10.1016/j.biortech.2018.10.056
33. Somin VA, Komarova LF, Kutalova AV. Protection of water objects against pollution with the use of sunflower growing waste. IOP Conference Series: Earth and Environmental Science. 2019;408:012038. https://doi.org/10.1088/1755-1315/408/1/012038
34. Somin VA, Betts SA, Komarova LF. Using of crop waste in the purification of water from phenol. Voda: khimiya i ekologiya = Water: chemistry and ecology. 2016;4:48–53. (In Russian)
Review
For citations:
Somin V.A., Komarova L.F., Kutalova A.V. Study of buckwheat husk application for water demineralisation. Proceedings of Universities. Applied Chemistry and Biotechnology. 2020;10(2):213-222. (In Russ.) https://doi.org/10.21285/2227-2925-2020-10-2-213-222
Views:
447
Email this article 