Structure and sorption activity of larch bark treated with green reagents
https://doi.org/10.21285/2227-2925-2023-13-1-124-132
Abstract
The paper describes the structure and sorption activity of larch bark following treatment with green reagents. The aim was to obtain sorbents from larch bark by means of chemical treatment. The study compared the effect of non-toxic and low-toxic extraction agents and reagents, such as water, hexane, ethanol and hydrogen peroxide, on the structure, sorption properties of the treated bark, as well as on the composition of the extracted substances. It was established that the process of bark extraction involves the transformation of its main components, leading to the formation of long-range ordered structures. The greatest structural changes were observed for the bark treated consecutively with ethanol and hydrogen peroxide, mainly due to the decomposition of hemicelluloses. Such treatment of the bark was revealed to contribute to the formation of a mesoporous structure. The methylene blue sorption of the treated bark is 6.5 times higher than that of the original bark. Studies of extracted substances using IR spectroscopy and GC-MS showed a similar composition of larch bark extracts obtained by aqueous and ethanol treatment, which contain mainly phenolic and alcohol compounds. In addition, the ethanol-peroxide solution contains esters and carboxylic acid derivatives. The hexane extract of larch bark was found to contain mainly terpenes and their derivatives, which are widely used as valuable components in medicine and have great potential as a source of biomaterials for green polymers.
Supporting agencies: The authors would like to thank Dr. Sci. B.N. Kuznetsov for useful discussion of the results, as well as Cand. Sci. G.N. Bondarenko, Cand. Sci. E.V. Mazurova and Cand. Sci. E.V. Elsufiev for their help in carrying out physicochemical studies of the samples. The authors express their gratitude for the provision of scientific equipment to the Krasnoyarsk Regional Center for Collective Use of the FRC KSC SB RAS. This work was financially supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Regional Science Fund (grant no. 20-43-242904) within the framework of the State Assignment of the Institute of Chemical Technology of the Siberian Branch of the Russian Academy of Sciences, FRC KSC SB RAS (project 0287-2021-0017).
About the Authors
S. I. Tsyganova
Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS
Russian Federation
Russian Federation
Svetlana I. Tsyganova - Cand. Sci. (Chemistry), Associate Professor, Senior Researcher, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS.
50/24, Akademgorodok, Krasnoyarsk, 660036
A. V. Levdansky
Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS
Russian Federation
Russian Federation
Alexander V. Levdansky - Cand. Sci. (Chemistry), Researcher, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS.
50/24, Akademgorodok, Krasnoyarsk, 660036
A. M. Skripnikov
Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS
Russian Federation
Russian Federation
Andrey M. Skripnikov - Junior Researcher, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS.
50/24, Akademgorodok, Krasnoyarsk, 660036
O. P. Taran
Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS
Russian Federation
Russian Federation
Oxana P. Taran - Dr. Sci.(Chemistry), Professor, Director, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS.
50/24, Akademgorodok, Krasnoyarsk, 660036
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Review
For citations:
Tsyganova S.I., Levdansky A.V., Skripnikov A.M., Taran O.P. Structure and sorption activity of larch bark treated with green reagents. Proceedings of Universities. Applied Chemistry and Biotechnology. 2023;13(1):124-132. (In Russ.) https://doi.org/10.21285/2227-2925-2023-13-1-124-132
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