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STUDY OF DIALYZABLE MELANOIDIN FRACTIONS IN AQUEUOS-ETHANOLIC D-LACTOSE - ARYL AMINE SYSTEMS

https://doi.org/ 10.21285/2227-2925-2017-7-2-181-184

Abstract

Dialyzable fractions of brown polymers synthesized in amino-carbonyl interaction of D-lactose with p-toluidine under condition of acid catalysis in aqueous-ethanolic media was studied by UV-Vis spectrophotometry. To study of the fraction’s compositions and their dialysis dynamics two parallel series spectra of dialysates were measured. It is obtained that non-nitrogenous derivatives in dialyzable fractions are presented as weakly colored products with furan structural fragments, the main nitrogenous component is p-toluidine eliminated by the Amadori rearrangement product’s degradation.

About the Authors

I. S. Cherepanov
Udmurt State University
Russian Federation


G. M. Abdullina
Udmurt State University
Russian Federation


References

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2. Yaylayan V.A., Kaminsky E. Isolation and structural analysis of Maillard polymers: caramel and melanoidin formation in glycine/glucose model system // Food Chem. 1998. V. 63, N 1. P. 25-31.

3. Kim J.-S., Lee Y.-S. The influence of pH on the color development of melanoidins formed from fructose/amino acid enantiomer model systems // J. Food Sci. Nutr. 2008. V. 13, N 2. P. 306-312. DOI: 10.3746/jfn.2008.13.4.306.


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For citations:


Cherepanov I.S., Abdullina G.M. STUDY OF DIALYZABLE MELANOIDIN FRACTIONS IN AQUEUOS-ETHANOLIC D-LACTOSE - ARYL AMINE SYSTEMS. Proceedings of Universities. Applied Chemistry and Biotechnology. 2017;7(2):181-184. (In Russ.) https://doi.org/ 10.21285/2227-2925-2017-7-2-181-184

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ISSN 2227-2925 (Print)
ISSN 2500-1558 (Online)